DOI > 10.5291/ILL-DATA.4-04-462

This proposal is publicly available since 05/27/2018

Title

Excitations in a geometrically frustrated molecular magnet in a field: Mapping the wavefunctions across the avoided crossing.

Abstract

Especially tantalizing molecular magnets are triangular antiferromagnetic (AFM) clusters, as they constitute the most basic geometrically frustrated magnet. We plan to do inelastic neutron scattering experiments on aligned single crystals containing an antiferromagnetic Cu(II) triangle to directly determine the tunnel splitting in a magnetic field. This tunnel splitting arises from a combination of Dzyaloshinkii-Moriya interactions and unequal exchange interactions in the presence of a magnetic field in the plane of the triangles.The proposed experiments will allow directly measuring the tunnel splitting at an avoided level crossing, as well as determining the wavefunctions of the involved states, resolving remaining questions concerning the spin Hamiltonian of this material.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

OCHSENBEIN Stefan and MUTKA Hannu. (2013). Excitations in a geometrically frustrated molecular magnet in a field: Mapping the wavefunctions across the avoided crossing.. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.4-04-462

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Metadata

Experiment Parameters

  • Environment temperature

    <0.1 K
  • Experiment energy

    7-10 A
  • Experiment moment

    0.16-1.15 A-1
  • Experiment res energy

    0.015 - 0.03 meV
  • Experiment res moment

    0.05-0.1 A-1

Sample Parameters

  • Formula

    • Na12[Sb2W18Cu3O66(H2O)3].46H2O
  • Consistence

    single crystal
  • Mass

    1000
  • Space

    C2/c
  • Unit cell A

    13.9956
  • Unit cell B

    23.2361
  • Unit cell C

    32.012
  • Alpha

    90
  • Beta

    99.2490
  • Gamma

    90
  • Container

    cylinder