Stabilization of Sr-manganese phases with an unusual manganese oxidation state
We have synthesized two Strontium-Mn(V) samples with blue-greenish colour formulated as Srx(MnO4)y(OH,F)n.The refinement of the X-Ray powder diffraction pattern suggests that the studied Strontium-Mn samples crystallizes according to the type of Hydroxylapatite with S.G.=P63/m. A characterization by neutron diffraction is necessarily required to accurately determine the positions and occupations of light elements such as oxygen and fluorine, hardly detectable by other techniques. The set of results obtained will allow us to propose the real composition of both compounds.
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HERNANDO GONZALEZ Maria; FERNANDEZ DIAZ Maria Teresa; GOMEZ RECIO Isabel; MATESANZ Emilio; PARRAS Marina and VARELA Aurea. (2016). Stabilization of Sr-manganese phases with an unusual manganese oxidation state. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-21-1104