Influence of dopant distribution on catalytic properties in Mn related hollandites
hollandite related materials have been found as effective catalysts for CO oxidation. In this sense, we have undertaken the study of the influence of doping on the catalytic CO oxidation of hollandite related compunds. In this sense, different doped hollandites, with a general formula KnMn1-xDxOd; (D = Fe, Ti y V), have been synthesized and characterized.It is worth emphasizing that all of them are active at room temperature in CO oxidation. A characterization by neutron diffraction is necessarily required to accurately determine the positions and occupations of oxygen atoms, hardly detectable by other techniques, as well as, the water molecules present in the tunnel.
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HERNANDO GONZALEZ Maria; FERNANDEZ DIAZ Maria Teresa; GOMEZ RECIO Isabel; GONZALEZ CALBET Jose Maria; PARRAS Marina and VARELA Aurea. (2018). Influence of dopant distribution on catalytic properties in Mn related hollandites. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-21-1115