Transition oxometallate hydrides: a new compound class
Due to the reductive nature of hydrogenation reactions, mixed hydridic oxoanions are difficult to realize. The reductive atmosphere tends to reduce the oxoanions, hindering access to such materials. However, we were able to synthesize four compounds of new mixed anionic hydrides, the oxometallate hydrides, by applying reaction control. Such a combination of hydrides with transition oxometallate anions, like tungstates or molybdates are to the best of our knowledge not realized so far. Here we present the first four representatives of this class: Rb3MoO4H, Rb3WO4H, Cs3MoO4H, Cs3WO4H. This new class of materials complements previous studies and are of fundamental interest. This study is expected to open up a wide variety of possible new similar compounds.
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KUNKEL Nathalie; MUTSCHKE Alexander and RITTER Clemens. (2021). Transition oxometallate hydrides: a new compound class. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-21-1170
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