DOI > 10.5291/ILL-DATA.5-22-804

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Title

Investigation of stable intermediates and reassembly step of the ADOR mechanism in zeolites

Abstract

Zeolites are a family of porous aluminosilicate materials that have found applications in many different technologies. Simulations predict the possibility of millions of zeolite topologies but only hundred of zeolite frameworks of all compositions are known so far. Some zeolite structures have been deemed as 'unfeasible' through classical synthesis methods. The ADOR (assembly¿disassembly¿organisation¿reassembly) process is an important tool to access zeolite structures, where a 3D parent zeolite materials is disassembled into 2d zeolite layers to then be reassembled into new structures through condensation. UTL is a key parent zeolite as it has produced multiple high-silica products through the ADOR method. Two final product formations of interest are that of IPC-2 and IPC-4 formed from UTL parent zeolite, with the mechanism of formation of great interest. Two slightly different intermediates, IPC-2P and IPC-1P, need to be investigated further to better comprehend the reassembly step as well as the role of disorder in the structures.

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

LAWRENCE Gaynor; RITTER Clemens and STANZIONE Max. (2023). Investigation of stable intermediates and reassembly step of the ADOR mechanism in zeolites. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-22-804

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