Structure Property Relationships of the Insulator-Insulator Transition in CeMnAsO1-xFx (x = 0.00 - 0.08)
CeMnAsO is a Mott insulator and an unusual insulator-insulator transition is observed at low temperature upon electron doping, by substituting F- for O2-. CeMnAsO1-xFx (x = 0 - 0.08) have been synthesised. Below the transition temperature, TII, the resistivity is observed to increase by > 3 orders of magnitude over a 5 K temperature range for CeMnAsO1-xFx (x > 0.03). The preliminary results strongly suggest that the unusual insulator-insulator transition is a result of many body localisation (MBL) of the electrons which has not been previously reported in a bulk electronic phase. The proposed MBL phase is only observed over a narrow doping range (x = 0.035 - 0.075 inclusive). We propose to investigate the electronic phase diagram of CeMnAsO1-xFx by determining if there is any correlation between TII and bond lengths/angles. We also want to verify the stoichiometry of the different phases and determine how the Mn spin transition changes with electron doping.
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MCLAUGHLIN Abbie; LAWRENCE Gaynor; RITTER Clemens and SIMPSON Struan. (2018). Structure Property Relationships of the Insulator-Insulator Transition in CeMnAsO1-xFx (x = 0.00 - 0.08). Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-23-707