DOI > 10.5291/ILL-DATA.5-23-763

This proposal is publicly available since 06/24/2026

Title

In situ monitoring of the oxygen content of dual phase oxygen transport membranes by thermogravimetry and neutron diffraction

Abstract

Combined in situ neutron diffraction and thermogravimetry at D1B will beused to track the change of the oxygen content in the dual-phase oxygen transport membrane material Ce0.8Pr0.2O2-x/La0.5Sr0.5Fe0.8Cu0.2O3. The sample shows deviating thermal behavior in comparision to CeREO2-x (RE = La, Nd, Sm, Gd) having together with Gd containig the highest oxygen permeation flux, but they differ totally in there thermal behavior. Neutron diffraction is needed to monitor the individual changes in the oxygen content in fluorite and perovskite phase.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

WIDENMEYER Marc; CHEN Guoxing; NASSIF Vivian; WEIDENKAFF Anke and Songhak Yoon. (2021). In situ monitoring of the oxygen content of dual phase oxygen transport membranes by thermogravimetry and neutron diffraction. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-23-763

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Metadata

Experiment Parameters

  • Environment temperature

    300 K - 1173 K; sample stable to 1473 K
  • Experiment energy

    1.28 A

Sample Parameters

  • Formula

    • Ce0.8Pr0.2O2 - La0.5Sr0.5Fe0.8Cu0.2O3
    • Ce0.8Nd0.2O2 - La0.5Sr0.5Fe0.8Cu0.2O3
    • Ce0.8Pr0.2O2-x
    • La0.5Sr0.5Fe0.8Cu0.2O3-x