Assessing the influence of Li+ carrier density and Li+ substructure on ionic conductivity of substituted halide spinel Li2+xSc2/3-xMgxCl4
Lithium conducting halide spinels got back into focus of solid electrolyte researchers when Li2Sc2/3Cl4 was rediscovered exhibiting three-dimensional diffusion pathways and a high room-temperature conductivity of 1.5 mS·cm-1. Within these halide spinels, the Li+ carrier density was tuned by metal ion self-doping introducing vacancies. Incorporation of external dopants is rarely known, hence the effects of aliovalent substitution is one of the prime focus to understand the effect of lithium substructure on the transport properties of halide electrolytes. In this proposed experiment, we want to investigate the Li2+xSc2/3-xMgxCl4 substitution series in terms of structure-property relationships to assess the influence of the Li+ substructure on the ionic conductivity as well as the overall impact of Mg2+ substitution.
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The recommended format for citing this dataset in a research publication is in the following format:
ZEIER Wolfgang; BANIK Ananya; HELM Bianca; ROSENBACH Carolin and SUARD Emmanuelle. (2021). Assessing the influence of Li+ carrier density and Li+ substructure on ionic conductivity of substituted halide spinel Li2+xSc2/3-xMgxCl4. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-23-773
This data is not yet public
This data is not yet public
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