In situ investigations of the hydrogenation of CaRh2
The formation of perovskite deuteride CaRhDx by two deuteration pathways with intermediate cubic CaRh2Dx or hexagonal CaRh2Dx will be followed by in situ neutron powder diffraction in a user supplied sapphire single-crystal cell at deuterium pressures up to 50 bar and temperatures up to 723 K. Rietveld analysis of diffraction data will allow the location of deuterium positions in the deuterides and the mapping of the complete reaction pathway of deuterium uptake and release.
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Holger Kohlmann; FINGER Raphael; GOETZE André; Thomas C. Hansen; SAVVIN Stanislav and WERWEIN Anton. (2018). In situ investigations of the hydrogenation of CaRh2. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-24-605