Reaction pathways of hydrogenation-dehydrogenation of InPd3 and FePd3 by in situ neutron diffraction
The hydrogen-induced atomic rearrangements in intermetallic compounds MPd3 (M = In, Fe) will be studied by in situ neutron powder diffraction. A user-supplied gas-pressure cell with laser heating installed on D20 will provide the means to collect diffraction patterns as a function of temperature (up to 600 K) and deuterium gas pressure (up to 100 bar) with a time resolution of two minutes. This will allow to identify intermediates including deuterium positions in the crystal structures and provide an understanding of the underlying principle of hydrogen-induced rearrangement in intermetallics. For InPd3, the series of superstructures of the cubic-close packing (ccp) TiAl3 type - ZrAl3 type - PbTl2Pd9 type - AuCu3 type is to be monitored upon hydrogen uptake. For FePd3, the effect of atomic order (Fe/Pd, AuCu3 type and Cu type) on hydrogenation and hydrogen-induced ordering will be elucidated. These reactions are of importance in hydrogen embrittlement of materials and in catalytic processes.
Please note that you will need to login with your ILL credentials to download the data.
Download DataThe recommended format for citing this dataset in a research publication is in the following format:
Holger Kohlmann; FINGER Raphael; GOETZE André; Thomas C. Hansen; PFLUG Christian and WERWEIN Anton. (2018). Reaction pathways of hydrogenation-dehydrogenation of InPd3 and FePd3 by in situ neutron diffraction. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-24-613
ILL has partnered with DataCite as the registration agency
for data persistent identifiers.