Unravelling the structure-transport correlations in Li3-xIn1-xZrxCl6
The rare-earth halides Li3MX6 (M = Y, Er, In; X = Cl, Br, I) show promising high potential electrochemical stabilities and ionic conductivities in the mS/cm range, which is comparable to the lithium thiophosphates. Currently, the knowledge about the impact of isovalent or aliovalent substitutions within these compounds is very limited, which is usually a very well-known strategy to tune the ionic transport properties. In preliminary data, we observed a significant enhancement in ionic conductivity of Li3InCl6 substituting In with Zr which needs further investigation. Therefore, we propose neutron diffraction experiments in the series of solid solutions Li3-xIn1-xZrxCl6 (x = 0-0.5) to correlate the structural impact of the Zr-substitution with the transport behaviour in order to determine the Li substructure and find structure-property relationships.
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ZEIER Wolfgang; BANIK Ananya; HELM Bianca and SUARD Emmanuelle. (2021). Unravelling the structure-transport correlations in Li3-xIn1-xZrxCl6. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-24-664
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