Neutron Powder Diffraction Study on Bi Doped Li7-xLa3Zr2-xBixO12 Garnet Solid Solutions with x = 0.1-1.0
The aim of this proposal is to analyze Bi doped Li7-xLa3Zr2-xBixO12 garnet solid solutions with x = 0.1-1.0, which were firstly synthesized in our group (unpublished). Neutron powder diffraction measurements will be coducted to study the Bi- and Li-ion distribution of samples with different Bi content. On the bases of the those data we would be finally able to correlate the crystal chemical with the electrochemical properties of the samples as studied by impedance spectroscopy. This will contribute to a deeper understanding of the structure-property relationship in LLZO garnets, and could be the starting point of the improvement of the electrochemical properties by crystal chemical engineering.
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RETTENWANDER Daniel; AMTHAUER Georg; REDHAMMER Guenther; SUARD Emmanuelle and WAGNER Reinhard. (2015). Neutron Powder Diffraction Study on Bi Doped Li7-xLa3Zr2-xBixO12 Garnet Solid Solutions with x = 0.1-1.0. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-26-216
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