DOI > 10.5291/ILL-DATA.5-31-2259

This proposal is publicly available since 07/16/2018

Title

Nuclear and magnetic study of Cobalt, Manganese and Copper Ferrite nanoparticles obtained by a new electrochemical method

Abstract

In the last decade, nanoparticles have attracted great interests in the scientific community due to their optical, electrical and magnetic properties. Cobalt ferrite has focused attention for its high crystalline anisotropy, high coercivity and moderate saturation magnetization, but most of its magnetic properties strongly depend on the size and shape of the nanoparticles, which are closely related to the preparation method. A new methodology based in the electrochemical synthesis has been developed in order to controlling particle size in the range 20-40 nm. We propouse a neutron diffraction study of particles obtained by this new method in order to localize the cobalt and iron atom in the octahedral and tetrahedral sites; relate the nanoparticle size with the magnetic behaviour and study the role of cobalt through the subtitution of this atom by nickel and manganese.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

SANCHEZ-MARCOS Jorge; HERRASTI Pilar; MAZARIO Eva; MENENDEZ Nieves and RODRIGUEZ VELAMAZAN Jose Alberto. (2013). Nuclear and magnetic study of Cobalt, Manganese and Copper Ferrite nanoparticles obtained by a new electrochemical method. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-31-2259

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Metadata

Experiment Parameters

  • Environment temperature

    2-650 K
  • Experiment energy

    1.594, 2.52

Sample Parameters

  • Formula

    • MnFe2O4
    • NiFe2O4
    • CoFe2O4
  • Consistence

    powder
  • Mass

    500
  • Space

    Fd-3ms
  • Unit cell A

    8.406
  • Unit cell B

    8.406
  • Unit cell C

    8.406
  • Alpha

    90
  • Beta

    90
  • Gamma

    90
  • Container

    cylinder