Crystal and Magnetic structure study in 3 novel tetrahaloferrate compounds based on bicycle amines with a long-range magnetic ordering.
Recently, the study and application of halometallate compound based on bicycle amines have injected new vitality to the field of molecular ferroelectric thin films. Within this approach we have prepared a series of compounds based on bicycle amines together with halometallate centers to have access to the long-range magnetic order. The inclusion of halometallate centers promote the occurrence of halide···halide and H··halide interactions can modify not only the exchange coupling path but also play a significant role in the stabilization of the crystal structure. Thus, in this proposal we ask for beam-time on the powder diffractometers D2B and D1B to address the question about cooperative magnetic effects, complex anion interaction, and magnetostructural correlation on (quinuclidine)[FeCl4], [(R)-3 Quinuclidinol][FeCl4] and (3-Quinuclidone)[FeCl4] compounds. With this objective we apply for 2 days of beam time on D2B and 1 day on D1B.
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GONZALEZ IZQUIERDO Palmerina; BEOBIDE Garikoitz; DE PEDRO DEL VALLE Manuel; FABELO ROSA Oscar Ramon and FERNANDEZ DIAZ Maria Teresa. (2019). Crystal and Magnetic structure study in 3 novel tetrahaloferrate compounds based on bicycle amines with a long-range magnetic ordering.. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-31-2673
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