DOI > 10.5291/ILL-DATA.5-32-779

This proposal is publicly available since 06/11/2018

Title

Magnetic correlations in Mn3GaC and Mn3GaCN

Abstract

Mn3GaC undergoes a first order antiferromagnetic-ferromagnetic (AF_FM) transition at Ti = 160 K and a second order ferromagnetic-paramagnetic (PM) transition at TC = 250 K. Substituting partially carbon with nitrogen [Mn3Ga(C0.85N0.15)]causes Ti to increase to 180 K whereas TC drops such that it lies virtually below Ti, i.e. long-range ferromagnetism does not occur and only strong ferromagnetic correlations can be observed in the temperature dependence of the magnetization. These materials show field induced transformations from the low-temperature AF state to the high temperature FM (or FM correlated) state giving rise to large magnetocaloric effects. Using polarization analysis and neutron depolarization, we aim to study the nature of magnetic correlations as the first order transition is approached and at high temperatures, above the second order transition, to examine whether mixed AF and FM correlations appear already at temperatures well in the PM regime.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

ACET Mehmet; CAKIR Oznur and WILDES Andrew. (2013). Magnetic correlations in Mn3GaC and Mn3GaCN. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-32-779

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Metadata

Experiment Parameters

  • Environment temperature

    10-500 (0.1) K
  • Experiment energy

    3.47/4.85

Sample Parameters

  • Formula

    • Mn3GaC
    • Mn3Ga(C0.85N0.15)
  • Consistence

    powder
  • Mass

    10000
  • Size

    3000
  • Surface

    1000
  • Space

    Pm3m
  • Unit cell A

    3.85
  • Unit cell B

    3.85
  • Unit cell C

    3.85
  • Alpha

    90
  • Beta

    90
  • Gamma

    90
  • Container

    cylinder