DOI > 10.5291/ILL-DATA.5-32-821

This proposal is publicly available since 12/12/2020

Title

Structure of Fe-Phthalocyanine encapsulated inside SWCNT

Abstract

FePc@SWCNT are peapods-like nanostructures composed Fe-phthalocyanine encapsulated inside Single-Walled Carbon Nanotube. This metallo-organic macrocycle (FePc) molecule exhibits not only optical but also structure depending magnetic properties. Through confinement inside the holow cavity of carbon nanotube, 1D chains of these molecules are created, with new confomationnal order and that are thus expected to exhibit specific properties (optical, magnetic). Preliminary XRD experiment have proven that FePc@SWCNT are filled with the guest molecules but also show a signature of confined 1D phase. We now aim at performing high resolution neutron diffraction (D16 instrument) on FePc@SWCNT in the range 2-320K, in order to fully identify the 1D phase, possible order/disorder transitions, and the associated magnetic properties.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

LOPES SELVATI Ana Carolina; alvarez; BANTIGNIES Jean Louis; CRISTIGLIO Viviana; LE PARC Rozenn and ROLS Stephane. (2015). Structure of Fe-Phthalocyanine encapsulated inside SWCNT. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-32-821

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Metadata

Experiment Parameters

  • Environment temperature

    [1.8-300]K
  • Experiment moment

    [0.1 - 2.5] Å^{-1}

Sample Parameters

  • Formula

    • C32H16FeN8