DOI > 10.5291/ILL-DATA.5-32-851

This proposal is publicly available since 06/12/2023

Title

Magnetic Rheo-SANS studies of hybrid ferrofluidic dispersions

Abstract

In order to understand the magnetoviscous effect in hybrid ferrofluidic dispersion it is important to have a knowledge of flow- and field-induced microstructure formation. In conventional ferrofluids (consisting of spherical nanoparticles) strong magnetoviscous effect can be observed due to the dipolar interaction and formation of aggregates such as chains, hexagonal pseudocrystals etc. With the aim to increase shear stability, conventional ferrofluids are doped with elongated magnetic nanoparticles to form hybrid ferrofluidic dispersions. It was found that hybrid ferrofluidic dispersions reveal enhanced magnetoviscous properties, expressed as a transition from sol-like to gel-like behavior upon increasing nickel nanorod content. In this proposal, we intend to study the nanorheological behavior of such hybrid ferrofluidic dispersions by means of Rheo-SANS in applied magnetic field. The aggregate formation due to the magnetic field and shear-induced rupture of these superstructures will be investigated for several hybrid ferrofluidic dispersions with varying concentration of spherical nanoparticles.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

ZAKUTNA Dominika; DISCH Sabrina; GRAEF Kevin and HONECKER Dirk. (2018). Magnetic Rheo-SANS studies of hybrid ferrofluidic dispersions. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-32-851

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Metadata

Experiment Parameters

  • Environment temperature

    ambient
  • Experiment energy

    6 Ang
  • Experiment moment

    0.01-3 nm-1
  • Experiment res energy

    10%

Sample Parameters

  • Formula

    • Ni nanorods
    • Fe2O3 nanospindles
    • CoFe2O4 nanospheres