DOI > 10.5291/ILL-DATA.6-02-593

This proposal is publicly available since 02/19/2025

Title

Water structure in 'water-in-salt'and 'water-in-bisalt' electrolytes

Abstract

This is a continuation proposal aiming to explore the local structure around water in 'water-in-salt' and 'water-in-bisalt' systems by performing a first difference experiment in samples prepared with H2O and D2O. A first experiment has been performed in D3 (6-02-577), but the data correction procedure is not straightforward and the limitations in the accessible low-Q range and the statistical quality of the data make difficult to obtain accurate information. Therefore, we ask for 3 days of beam time in D7 in order to obtain good data at low Q and 1 day in D4 to obtain the complete S(Q) for the deuterated samples. The new data will serve also as a reference to analyse unambiguously the D3 data, providing a set of reliable S_HX(r) and g_HX(r) functions that will be used to determine the ordering of the ions around water.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

SABOUNGI Marie-Louise; CUELLO Gabriel; DOBOSZ Alexandra; GONZALEZ Miguel Angel; HENNET Louis; MANGIN-THRO Lucile; PRICE David L. and YAMAMURO Osamu. (2019). Water structure in 'water-in-salt'and 'water-in-bisalt' electrolytes. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.6-02-593

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Metadata

Experiment Parameters

  • Environment temperature

    290-350 K
  • Experiment energy

    3.12
  • Experiment moment

    0.15-3.9 AA-1
  • Experiment res energy

    -
  • Experiment res moment

    As available

Sample Parameters

  • Formula

    • (CF3SO2NLiSO2CF3)0.75(CF3SO3Li )0.25(D2O)2
    • (CF3SO2NLiSO2CF3)(H2O)2.7
    • (CF3SO2NLiSO2CF3)(D2O)2.7
    • (CF3SO2NLiSO2CF3)0.75(CF3SO3Li )0.25(H2O)2