DOI > 10.5291/ILL-DATA.6-07-24

This proposal is publicly available since 02/22/2022

Title

Forced water intrusion into deformable hydrophobic nanopores

Abstract

Water in hydrophobic confinement is of general interest for industrial applications as well as the understanding of biological matter and more generally in the field of soft condensed matter. Ordered hydrophobic nanoporous materials provide well defined geometries to study water in hydrophobic confinement. While water confined in hydrophilic nanopores has been extensively studied, water confined in highly hydrophobic nanopores has been rarely considered especially because of the high pressure required to fill hydrophobic nanopores. The goal of this proposal is to quantify the deformation of hydrophobic grafted MCM41 nanoporous material upon water forced intrusion. These deformation measurements will provide information on the impact of confined water and interfacial energy on the mechanical properties of the confining material, a better understanding of the mechanics at pore scale and intrusion mecanism.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

PICARD Cyril; CRISTIGLIO Viviana; LUDESCHER Lukas; MICHEL Loic and PARIS Oskar. (2017). Forced water intrusion into deformable hydrophobic nanopores. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.6-07-24

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Metadata

Experiment Parameters

  • Environment temperature

    Room Temperature
  • Experiment energy

    4.7Å
  • Experiment moment

    0.04 to 0.45 Å-1
  • Experiment res energy

    1% lambda resolution
  • Experiment res moment

    0.01Å-1

Sample Parameters

  • Formula

    • SiO2+ CH3(CH2)7Si(CH3)2Cl (10% organic fraction)