DOI > 10.5291/ILL-DATA.7-01-371

This proposal is publicly available since 06/01/2018

Title

Tetrahedron dynamics in a series of approximant crystals to the icosahedral quasicrystal i-AlCuSc

Abstract

The AlCuSc system features approximant phases to icosahedral quasicrystals. These phases have almost identical composition and consist of the same cluster building blocks (Tsai type clusters). The innermost shell of these clusters is a symmetry breaking tetrahedron which has been shown to reorient dynamically. The approximant phases differ in the exact arrangement of the Tsai type clusters, thus giving rise to different reorientation schemes of the tetrahedral shells. Therefore it becomes possible to investigate the direct influence of the cluster arrangement on the tetrahedron dynamics as well as the changes in the tetrahedron-tetrahedron correlations-mechanisms that come into play for stabilizing quasicrystals and approximants

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

EUCHNER Holger; BEUTIER Guillaume; DE BOISSIEU Marc; GOLDMAN Alan; HIROTO Takanobu; LIU Dan; LORY Pierre Francois and ROLS Stephane. (2013). Tetrahedron dynamics in a series of approximant crystals to the icosahedral quasicrystal i-AlCuSc. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.7-01-371

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Metadata

Experiment Parameters

  • Environment temperature

    0-500 K
  • Experiment energy

    5.5A / 2.4A
  • Experiment moment

    0-2.5/0-5 A-1
  • Experiment res energy

    0.1meV / 0.4 meV
  • Experiment res moment

    0.2 A-1

Sample Parameters

  • Formula

    • MgScZn
    • Al40.5Cu45.0Sc14, Al36.4Cu48.1Sc15.5
    • Cd6T6
  • Consistence

    polycristalline; powder
  • Mass

    8000; 2400
  • Size

    1000; 0.25-0.3
  • Surface

    100
  • Space

    Im3bar
  • Unit cell A

    14.0
  • Unit cell B

    14.0
  • Unit cell C

    14.0
  • Alpha

    90
  • Beta

    90
  • Gamma

    90
  • Container

    cylinder (with double walls)