DOI > 10.5291/ILL-DATA.7-03-156

This proposal is publicly available since 07/15/2024

Title

Probing dynamics of water mass transfer in covalent triazine-based framework water-splitting materials by neutron spectroscopy

Abstract

We propose to study diffusive dynamics in the natrium superionic conductor (NASICON) materials Na3ScxZr2-x(SiO4)2-x(PO4)1+x and Na2ScyZr2-y(SiO4)1-y(PO4)2+y by means of quasielastic neutron scattering (QENS. One of the advantages of the NASICON materials is the variety of compositions within the general formula NaxM2(SiO4)z(PO4)3-z. By substituting on the M site, the electrochemical and ion conduction properties can be tuned for specific applications. These materials have been used as electrodes and electrolyte, presenting homogeneous electrode/electrolyte interface and high stability.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

ZBIRI Mohamed and GUILBERT Anne. (2019). Probing dynamics of water mass transfer in covalent triazine-based framework water-splitting materials by neutron spectroscopy. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.7-03-156

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Metadata

Experiment Parameters

  • Environment temperature

    2 - 600 K
  • Experiment energy

    As available
  • Experiment res energy

    As available

Sample Parameters

  • Formula

    • Na3ScxZr2-x(SiO4)2-x(PO4)1+x (x=0, 0.25, 1)
    • Na2ScyZr2-y(SiO4)1-y(PO4)2+y (y=0, 0.25, 1)