Anion Reorientations in Na2B12H12 at Elevated Pressure
Under elevated pressure the structure of the solid-ionic conductor Na2B12H12 can be manipulated providing a new dimension for the rational design of such materials with better conductivity. Our group has recently characterised a high pressure phase of Na2B12H12, which can be stabilised at ambient pressure and adopts a fcc-like structure favourable for higher conductivity and faster dynamics. Here we propose to study reorientational anion motions in Na2B12H12 undergoing the pressure-induced phase transition. The aim of our study is to elucidate the connection between the anion supported conduction mechanism, anion reorientational mobility and crystal structure of this solid-state electrolyte.
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BURANKOVA Tatsiana; EMBS Jan P; Bernhard Frick; HAGEMANN Hans; MOURY Romain and REMHOF Arndt. (2018). Anion Reorientations in Na2B12H12 at Elevated Pressure. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.7-03-172
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