INS study of solvatochromic effect induced by host-guest interactions in zeolites
The aim of this proposal is to understand the role of zeolite structure and the nature of extraframework cations (M=Li+, Na+, K+, Rb+, Cs+)on the solvent behavior of zeolites. The goal is planned to be achieved by a combined experimental and modelling study of salicylidenaniline molecule sorbed in cation-exchanged zeolites. The molecule, which is well known for its solvatochromic and photochromic properties, is expected to be a sensitive indicator of the details of host-guest interactions. Results of the study performed with a large palette of methods of electronic and vibrational spectroscopies and assisted by molecular modeling, will provide new data allowing a better understanding of reactivity of zeolites. The outcome of the project should provide a new insight on the acid-base characteristics of non-Brønsted acid zeolite and on the parameters controlling these characteristics.
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MOISSETTE Alain; HUREAU Matthieu; JIMENEZ RUIZ Monica and JOBIC Herve. (2013). INS study of solvatochromic effect induced by host-guest interactions in zeolites. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.7-05-408
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