DOI > 10.5291/ILL-DATA.7-05-413

This proposal is publicly available since 07/14/2018

Title

Investigating the Strengths of Different Halogen Bonds in Physisorbed Layers

Abstract

Halogen bonds are an exciting, relatively new class of supramolecular, non-bonded interaction. However, their application in physisorbed systems remains largely unexplored. Here we aim to obtain information on the strengths of different halogen bonds in physisorbed monolayers on graphite, and address the effect of halogen type and degree of fluorination on the interaction strength. This information is vital to characterizing the halogen bond in monolayer systems, and has proved impossible to obtain using techniques other than neutron spectroscopy.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

CLARKE Stuart M.; BREWER Adam; Kathryn Browning; JIMENEZ RUIZ Monica; JOHNSON Mark Robert and TRUSCOTT Chris. (2013). Investigating the Strengths of Different Halogen Bonds in Physisorbed Layers. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.7-05-413

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Metadata

Experiment Parameters

  • Environment temperature

    10 K
  • Experiment energy

    25 - 410 meV
  • Experiment res energy

    0.01 meV

Sample Parameters

  • Formula

    • 4,4'-bipyridyl physisorbed on graphite
    • 1,4-diiodobenzene physisorbed on graphite
    • 1,4-dibromotetrafluorobenzene physisorbed on graphite
    • 1,4-diiodotetrafluorobenzene physisorbed on graphite
  • Consistence

    compacted solid
  • Container

    Cylinder