DOI > 10.5291/ILL-DATA.7-05-569

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Title

Mobility of pi-complexes of C2H4 with Ag+ species in Ag-zeolites by Quasielastic Neutron Scattering

Abstract

Ag-zeolites have obtained an increasing interest due to their unique capacity for ethylene/ethane purification, which is an essential process for the petrochemical industry. Very specific properties and the stability of Ag(C2H4)+ complexes within zeolites pores are highly sensitive to the dimension and geometry of such pores. Along with INS data already investigated, detailed information can be obtained by studying the molecular mobility of ethylene¿s internal rotations on an Ag+ site and even translational migration among the sites at the scale of 1 ps. Here we propose to perform the characterization of the molecular mobility of ethylene bound to Ag+ site in zeolites CHA, LTA and RHO by Quasielastic Neutron Scattering, which has never been applied in these specific systems before as far as we know.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

E SILVA DE ALMEIDA Gabrielli maria; Alberto Barros Pardo; Teresa Blasco; A de Marcos-Galán; JIMENEZ RUIZ Monica; OLLIVIER Jacques; REY Fernando and SASTRE German Ignacio. (2023). Mobility of pi-complexes of C2H4 with Ag+ species in Ag-zeolites by Quasielastic Neutron Scattering. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.7-05-569

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