DOI > 10.5291/ILL-DATA.9-10-1291

This proposal is publicly available since 07/09/2018

Title

Connecting the adsorbed structure of a model additive, hexylamine, with its exceptional anti-corrosion behaviour on nickel oxide.

Abstract

This proposal seeks to characterise the adsorbed structure of a simple amine such as has been long used in additive systems for anti-corrosive applications at the nickel oxide / aqueous interface. With little work yet done towards understanding the structural and composition characteristics of adsorption on nickel oxide from solution, neutron reflection offers an unprecedented and unique opportunity to illuminate this molecular layer under different environmental conditions.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

Mary H. Wood; BARKER Robert; CLARKE Stuart M.; GUTFREUND Philipp; WELBOURN Rebecca and ZARBAKHSH Ali. (2013). Connecting the adsorbed structure of a model additive, hexylamine, with its exceptional anti-corrosion behaviour on nickel oxide.. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-10-1291

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Metadata

Experiment Parameters

Sample Parameters

  • Formula

    • Nickel oxide (on a nickel-coated silica substrate): NiO
    • Water: H2O
    • Deuterated water: D2O
    • Sodium nitrate: NaNO3
    • Nitric acid: HNO3
    • Sodium hydroxide: NaOH
    • Hexylamine: C6H15N
  • Consistence

    solid/liquid interface
  • Mass

    50000
  • Size

    100000
  • Container

    liquid/solid neutron reflectometry cell