PEO-PLA and Cn-PEO-PLA block copolymers as building units for soft patchy colloids
We plan to use spontaneous self-assembly of tailor-made amphiphilic diblock and asymmetric triblock copolymers to form soft patchy colloids following a theoretical approach of Cappone et al. We aim at mixed micelles of PEO-PLA diblock and Cn-PEO-PLA triblock copolymers by exploiting the difference between the hydrophobic blocks Cn and PLA in entropic and enthalpic contributions to the free energy of micellisation. We will investigate the association behaviour of the individual components as well as perform first exploratory runs with mixed micelles using SANS at D11.
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STELLBRINK Joerg; SCHWEINS Ralf and WILLNER Lutz. (2018). PEO-PLA and Cn-PEO-PLA block copolymers as building units for soft patchy colloids. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-10-1554
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