DOI > 10.5291/ILL-DATA.9-10-1583

This proposal is publicly available since 07/25/2024

Title

Understanding the formation of colloidal quasicrystals

Abstract

Soft quasicrystals extend the length scale of quasicrystals from the atomic scale for metallic quasicrystals to the mesoscopic scale, and are interesting because the underlying principles governing quasicrystal formation might be much simpler to identify compared to metallic systems. We plan to study the formation of colloidal quasicrystals with Rheo-SANS using a Couette cell, where radial and tangential scattering patterns can be measured. Concentrated solutions of the block copolymers (PI-b-PS-OH, PI-b-PS-UPY) will be prepared in diethylphthalate d14. To measure the form factor in concentrated solution we will prepare samples in concentrated solution which contain different ratios of diethylphthalate d14 and diethylphthalate h14 (contrast variation). A concentration series from concentrated to dilute solution of the block copolymers (PI-b-PS-OH, PI-b-PS-UPY) will be prepared for the PI-PS system in diethylphthalate d14 (determining the ratio λ and determining the type of structure factor for the PI-PS system).

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

JURCZYK Tobias; DULLE Martin; PORCAR Lionel; RADULESCU Aurel and SCHWEINS Ralf. (2019). Understanding the formation of colloidal quasicrystals. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-10-1583

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Metadata

Experiment Parameters

  • Environment temperature

    15 °C to 70 °C

Sample Parameters

  • Formula

    • 1wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 0.5wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 25wt (C5H8)210(C8H8)154OH in C12D14O4
    • 20wt ( 70% (C5H8)210(C8H8)154OH und 30% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 25wt (C5H8)210(C8H8)154OH in 80%C12D14O4 und 20%C12H14O4
    • 25wt (C5H8)210(C8H8)154OH in 60%C12D14O4 und 40%C12H14O4
    • 25wt (C5H8)210(C8H8)154OH in 40%C12D14O4 und 60%C12H14O4
    • 25wt (C5H8)210(C8H8)154OH in 20%C12D14O4 und 80%C12H14O4
    • 20wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 15wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 10wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 5wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 0.25wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 17.5wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 12.5wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4
    • 7.5wt ( 50% (C5H8)210(C8H8)154OH und 50% (C5H8)210(C8H8)154C13H19O3N5) in C12D14O4