DOI > 10.5291/ILL-DATA.9-11-1706

This proposal is publicly available since 09/29/2019

Title

Structure determination of microcapsules with advanced temperature responsive behavior

Abstract

Nanocapsules are of special interest in the field of colloidal science. When synthesized from a thermoresponsive polymer like poly(N-isopropylacrylamide) (PNIPAM) a thermally induced uptake and release mechanism is imaginable. We performed the first small angle neutron scattering experiments including contrast variation measurements to investigate the structure of this unique species. Now we aim for advanced properties by introducing a second thermoresponsive polymer, namely poly(N-isopropylmethacrylamide) (PNIPMAM). Not only the different polymer type, but also the architecture in which both polymers are combined in the shell might have an influence on the capsule properties. Therefore we want to investigate capsules with a double-shell structure and a classical copolymer shell and compare these results with the homopolymer analogues.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

RICHTERING Walter; DUBBERT Janine; GELISSEN Arjan; LINDNER Peter and SCHMID Andreas. (2014). Structure determination of microcapsules with advanced temperature responsive behavior. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-11-1706

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Metadata

Experiment Parameters

  • Experiment energy

    6 A
  • Experiment moment

    0.001-0.08 1/A

Sample Parameters

  • Formula

    • silica-core/PNIPMAM-shell and corresonding hollow sphere
    • silica-core/PNIPMAM-PNIPAM- copolymer-shell and corresonding hollow sphere
    • silica-core/PNIPAM-shell and corresonding hollow sphere