DOI > 10.5291/ILL-DATA.9-11-1938

This proposal is publicly available since 02/07/2025

Title

Conformation of single-chain nano-particles surrounded by linear chains: reversible vs irreversible bonds

Abstract

We want to check the coarse-grained simulations prediction of crumpled globular-like conformations of SCNPs when they are surrounded by linear polymer chains in bulk conditions for both, reversible and irreversible SCNPs. We want to determine the dependence of the scaling exponent with the degree of cross-linking and verify the a priori unexpected result that for equal fraction of reactive monomers, the compaction degree is higher for SCNPs forming reversible bonds than for SCNPs obtained by irreversible crosslinking.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

MORENO Angel; Arantxa Arbe; COLMENERO Juan; FORMANEK Maud; Paula Malo de Molina; PACIOLLA Mariarita; POMPOSO Jose A.; PORCAR Lionel and SHAFQAT Numera. (2020). Conformation of single-chain nano-particles surrounded by linear chains: reversible vs irreversible bonds. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-11-1938

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Metadata

Experiment Parameters

  • Environment temperature

    300 to 460K
  • Experiment moment

    0.002 to 1 inv A

Sample Parameters

  • Formula

    • PMMA-based NPs in dPMMA linear