Kinetic studies of the Trost ligand particpating in a catalytic cycle
The aim is use time-resolved SANS to monitor the changes in aggregation structure of the Trost ligand[1] Pd-catalyst [(DACH-phenyl-TSL)Pd+(ç3-C6H9)]BArF- 1 (Figure 1 left) in situ whilst it is participating in a catalytic cycle. The experiments will help to reveal further important details of Pd-Trost ligand oligomer structure for (1)n whilst participating in a catalytic cycle. This will provide valuable information for taming this system so that its power can be reliably and reproducibly harnessed for synthesis.
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EASTOE Julian; ALEXANDER Shirin; GRILLO Isabelle; JAMES Craig; RACYS Daugirdas; Gregory N. Smith and YAN Ci. (2013). Kinetic studies of the Trost ligand particpating in a catalytic cycle. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-12-344
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