DOI > 10.5291/ILL-DATA.9-12-397

This proposal is publicly available since 06/26/2020

Title

Methane adsorption in porous Metal Organic Frameworks

Abstract

The proposal is to use SANS to detect on a local scale the pore filling mechanism of methane in a new ultra-high adsorption capacity substrate (metal organic framework) that is mooted for gas storage systems. Unlike the situation with rigid substrates where the local properties of the adsorption process can be observed by SAXS, these systems swell significantly, making it necessary to use contrast variation to distinguish between the substrate and the profile of the condensed gas.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

GEISSLER Erik; CZAKKEL Orsolya; LASZLO KRISZTINA and PORCAR Lionel. (2015). Methane adsorption in porous Metal Organic Frameworks. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-12-397

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Metadata

Experiment Parameters

  • Environment temperature

    253 K

  • Experiment energy

    6 Å

  • Experiment moment

    0.005 - 0.3 Å^-1

  • Experiment res energy

    10%

  • Experiment res moment

    10%

Sample Parameters

  • Formula

    • Metal Organic Framework HKUST-1 C18H6Cu3O12
    • methane CH4
    • deuterated methane CD4

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