DOI > 10.5291/ILL-DATA.9-12-399

This proposal is publicly available since 05/12/2020

Title

Self Assembly in Deep Eutectic Solvents

Abstract

Deep Eutectic Solvents (DES) are molecular mixtures similar to ionic liquids, having melting points below room temperature. However instead of being composed of a salt, the mixture contains two molecules with strong interactions that hinder formation of an ordered crystalline network. DES share many of the features of ionic liquids (low vapour pressure, adjustable polarity, etc) which make them interesting as green solvents while being far less toxic than typical ionic liquids. There is also some evidence that DES may form within the crowded cellular environment and could assist in solubilizing biological species in an intermediate environment between that of the hydrophobic phospholipids and highly polar water rich regions, particularly assisting survival under extreme conditions e.g. low temperature or drought where the water content of cells is restricted. Compared to ionic liquids, some DES are tolerant of high water content. Here we propose to examine the self assembly of a common surfactant, C12TAB, in a water containing DES as a function of water content.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

Karen J Edler; ARNOLD Tom; JACKSON Andrew; PORCAR Lionel and Adrian Sanchez-Fernandez. (2015). Self Assembly in Deep Eutectic Solvents. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-12-399

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Metadata

Experiment Parameters

  • Environment temperature

    25C
  • Experiment moment

    0.005 - 0.7

Sample Parameters

  • Formula

    • Malic Acid/Choline Chloride Mixture