DOI > 10.5291/ILL-DATA.9-13-535

This proposal is publicly available since 09/19/2019

Title

Protein-surfactant co-adsorption at the oil/water interface: exploring neutron reflection measurements

Abstract

The proposal seeks to develop Figaro as a neutron reflection instrument to undertake the oil-water interface studies using polypeptide-surfactant mixtures as an object of study. As the start, the interfacial tension values are modest, so that the interfacial structures are relatively easy to determine. The ultimate technical challenge lies in the ability to unravel meaningful information when the interfacial tension values are getting lower. As before, we will also test how the combined use of deuterium substitution to the surfactant and solvent help define the interfacial structures. Relevant publications are: Chen, C.X.; Hu, J.; Zhang, S.Z.; Zhou, P.; Zhao, X.C.; Xu H.; Zhao, X.B.; Yaseen, M.; Lu, J.R., Biomaterials 2012, 33, 592-603. Han, S.; Xu, W.; Cao M.; Wang J. Xia, D.; Xu, H.; Zhao, X.; Lu, J.R., Soft Matter 2011, 8, 645-652 . Han, S.; Cao, S.; Wang, Y.; Wang, J.; Xia, D.; Xu, H.; Zhao, X.; Lu, J.R., Chem. Euro. J. 2011, 17, 13095-13102. Wang, S.J.; Ge, X.; Xue, J.Y.; Fan, H.M.; Mu, L.J.; Li, Y.P.; Xu, H.; Lu, J.R., Chem. Mater. 2011, 23, 2466-2474. Zhao, X.B.; Pan, F.; Xu, X.; Yaseen, M.; Shan, H.; Hauser, C.A.E.; Zhang, S.; Lu, J.R., Chem. Soc. Rev. 2010, 39, 3480.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

Jian Ren Lu; CAMPANA Mario; Richard A. Campbell; FRAGNETO Giovanna; LI Ruiheng; LI Zongyi; LU Zhiming and PAMBOU Elias. (2014). Protein-surfactant co-adsorption at the oil/water interface: exploring neutron reflection measurements. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-13-535

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Metadata

Experiment Parameters

  • Environment temperature

    10 - 40 C with water thermostat control
  • Experiment energy

    Normal reflection
  • Experiment res moment

    0.01 - 0.3 angstrom-

Sample Parameters

  • Formula

    • Eggshell membrane polypeptides, d- and h-C16 oils and d- and h-SDS