DOI > 10.5291/ILL-DATA.9-13-642

This proposal is publicly available since 11/21/2021

Title

Using neutron reflectivity to understand the structural basis for the rheology of molten chocolate

Abstract

Molten chocolate is a semi-solid suspension of (mostly) sugar, but also cocoa and milk solids in oil. In order to allow the sugar grains to flow past each other, either when the chocolate is being made, or when it has melted in your mouth, it also contains surfactant additives. These are mostly naturally occuring products, such as lecithin, which comprises lipids which are found at surfaces in nature, but also some polymeric molecules such as PGPR. Rheology measurements suggest that the two additives behave cooperatively. Building on previous SANS measurements, we will use neutron reflectivity to determine how the two components are distributed at the oil/sucrose interface. This will allow us to test a model we have derived using polymer physics to explain how the additives lubricate the sugar grains. Understanding this would enable nicer, healthier and cheaper chocolate to be manufactured.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

TITMUSS Simon; I.Manasi and SAERBECK Thomas. (2016). Using neutron reflectivity to understand the structural basis for the rheology of molten chocolate. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.9-13-642

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Metadata

Experiment Parameters

  • Experiment moment

    0.008-0.25A^-1
  • Experiment res moment

    5%

Sample Parameters

  • Formula

    • lecithin
    • sucrose coated silicon substrates with/without permalloy under layer
    • glyceryl trioctonoate
    • polyglycerylricinoleate (PGPR