DOI > 10.5291/ILL-DATA.EASY-929

This proposal is publicly available since 08/31/2026

Title

Spin excitations in the valenced delocalized molecular magnet Fe-14

Abstract

Molecular magnets are finite clusters of metal ions distributed within a crystalline lattice such that their magnetic properties are molecular. Over the last decades such systems have represented ideal test beds to investigate the collective behaviour of unpaired electrons using inelastic neutron scattering. With ILL proposal 4-06-8, the first investigation of the spin dynamics within a molecular magnet exhibiting electron delocalisation due to mixed valency began. With this easy-proposal, we seek to finalize that investigation. The availability of a isotope-enriched sample will allow us to perform higher-resolution measurements with low incoming energy to investigate thermally populated transitions and complete the picture of the spin dynamics in a valence-delocalised molecular magnet.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

Rasmus Tang Christiansen and OLLIVIER Jacques. (2021). Spin excitations in the valenced delocalized molecular magnet Fe-14. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.EASY-929

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Metadata

Experiment Parameters

  • Experiment energy

    5-10 Å
  • Experiment res energy

    0.01

Sample Parameters

  • Formula

    • [FeTp(CN)3]8[Fe(D2O)(DMSO)]6 where Tp- = hydrotris(pyrazolyl)borate, DMSO = dimethyl sulfoxide