DOI > 10.5291/ILL-DATA.5-24-708

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Title

Proton disorder in the double hydroxide perovskite CuSn(OH)6 under hydrostatic pressure

Abstract

We have identified a transition-metal hydroxide perovskite that combines correlated proton disorder with geometrically frustrated S=1/2 magnetism of Cu2+ ions. We expect that similarly to water ice, the proton network in CuSn(OH)6 may order under hydrostatic pressure. Therefore we are interested in measuring neutron diffraction under pressure in the Paris-Edinburgh cell up to ~5 GPa at temperatures down to ~80 K to look for structural changes in the proton network. Both deuterated and protonated phase-pure powder samples are already available. If any such changes are revealed, their influence on magnetic properties will be addressed in follow-up studies.

Experimental Report

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Data Citation

The recommended format for citing this dataset in a research publication is in the following format:

Dmytro Inosov; DOERT Thomas; Thomas C. Hansen; KULBAKOV Anton; PAVLOVSKII Nikolai and Darren C. Peets. (2023). Proton disorder in the double hydroxide perovskite CuSn(OH)6 under hydrostatic pressure. Institut Laue-Langevin (ILL) doi:10.5291/ILL-DATA.5-24-708

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